British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.

For several reasons, there are pieces which cannot be pressed: they may be required very thin, or their shape is such, that the potter cannot reach all the parts to take the impression conveniently. In this case he must adopt the following plan. The mould is tied up, and filled with liquid clay through an opening left in the top. The plaster rapidly absorbs the water, and a deposit of solid clay adheres to the surface. This soon increases in thickness; and when the potter thinks it is sufficient, he pours out the slip which is in excess. The piece soon hardens, and when it begins to contract, it is then time to remove it from the mould. This process has the advantage of giving a uniform thickness, and as there is no other pressure than that caused by the absorption of the plaster surface, there is a better chance for the piece to contract equally, and on this account this method (called casting) is preferred for articles which require a neat execution. In some cases it is cheaper than ordinary pressing; but the drawback is, the excessive contraction or diminution of bulk to which the ware thus made is subjected. An irregular contraction is the source of most of the defects attending the ceramic manufacture, and it is worth explaining the causes, of which there are three. I have already mentioned that natural clays, which have remained in a damp soil for ages, contain materials in a hydrous state, i.e. combined with water, which sometimes increases their bulk considerably. These are unstable compounds, and may be destroyed by thoroughly drying them. Some other materials used in pottery may be artificially combined with water, as would be the case, if ground in it for an unnecessary length of time. The second reason is, the interposition of the uncombined water between the solid particles of the clay, and as this cannot be worked without it, this cause of shrinking cannot be avoided. It will be easily understood, that when the water in the mixture evaporates, the solid particles, under atmospheric pressure, will move to take its place, and this effect will continue as long as they find enough moisture to assist in their free motion. The consequence is, that the mass shrinks more and more, till the contraction is stopped by the inability of the particles to move farther; and this happens before the pieces are completely dry. From that state to complete dryness, the evaporation of the remaining water will leave small holes, which will make the texture of the ware porous, and prone to absorb any liquid with which it may come in contact.

The shrinkage in the raw state then is mechanical, and distinct from that which takes place in the oven under the influence of heat. Under this agency the particles enter into combination, and if the process is carried far enough, the ware may become partially vitrified and acquire a certain amount of transparency. The more perfect the vitrification, the closer will be the contact of the particles, and consequently the greater the diminution of bulk. From these causes, the total contraction may vary from one-sixteenth to one-fifth of the original model. The least will belong to ware pressed with stiff clay gently fired; the greatest, to that cast with liquid slip and brought to the vitrified state. In these last, the shrinkage is greater in height than in width, a fact explained by the weight of the upper portions acting vertically to assist the closer contact of the particles in the under-structure, when the same opposes their free action in an horizontal direction. In making the models, care should be taken to bring the contraction to a common centre, or if there are several, to strengthen sufficiently the connecting parts.

After the drying of the ware, the next operation consists in placing it in saggers, which, as I have said, are made of common fire-clay, and of a form and size to suit the different articles which they are intended to hold. A certain thickness of flint or sand is placed at their bottom for the purpose of giving them a firm bed, and as it is the interest of the manufacturer to make the same firing answer for the greatest quantity of goods, care is taken to fill the saggers as far as is safe. The placing of the ware is done at the outside of the ovens, and when these are to be filled, the saggers are quickly arranged one over the other in columns, called "bungs," each sagger forming the cover for the one immediately underneath. A small roll of soft clay placed between makes them stand better, and at the same time prevents the ashes carried by the draught from finding their way into the interior, and damaging the contents.

In ancient times, the ovens, intended to hold few pieces, were very small; but as the potters became more experienced, the sizes were gradually increased, and now-a-days some of them are not less than 19 feet in diameter. The quality of fuel had, of course, a great deal to do with their mode of construction. Now, however, that coals are acknowledged to contain more heat, and to be cheaper than wood, the ovens are generally built in a cylindrical form, with several mouths or feeders disposed at equal distances on the outer circumference, the upper part being covered by a semi-spherical dome or vault, to keep the heat inside and reverberate it downwards. This construction is very simple, the only complication being in the arrangement of flues under the bottom of the oven, so as to throw into that part a portion of the heat, which otherwise would be liable to accumulate towards the top.

The firing must be conducted very slowly at first, to prevent a too sudden evaporation of the damp, which would cause the splitting of the goods. This being done, the heat is raised gradually, care being taken to feed the mouths with fuel as quickly as it is consumed. It requires an experienced fireman, to see that one part of the oven does not get in advance of the other. He manages this by throwing in a certain quantity of air through small openings in the brick-work, which are shut or left open according to circumstances. Whatever may be the construction of the oven, the quantity of air mixed with the gas produced by the combustion of fuel causes the atmosphere to be reductive of oxidizing; which means that the different materials submitted to the heat would, in consequence of an abundance of carbon, have a tendency to be deprived of their oxygen and return to a metallic state, or that by firing in presence of an excess of air or carbonic acid, they would be kept in a high state of oxidation. It is fortunate that all classes of English pottery, without exception, require, or are not injured by, an oxidizing fire, which is the most economical way of firing, since by it all the gases are completely burnt inside the oven without any waste of fuel. By a better application of this principle, Messrs. Minton have introduced a new oven, in which the fuel is so completely utilized, that it requires only one half of the usual quantity of coals, besides doing away with the dense smoke, which is the annoyance of the district.

By the first fire to which it is exposed, the ware is converted into what is termed, from the French, biscuit– an incorrect name, as it seems to imply that it has already been fired twice, when, in fact, it has been only fired once. Some classes of pottery do not require more than a single firing, as, for instance, the common terra cotta and stoneware. However, for all our English ware it is necessary to have two fires, for the following reasons: First, the necessity for getting a denser texture of the ware by submitting it to a strong heat, lest the glazes which are to be melted on their surface, and which thereby become very dense and most contractible, should not agree with the more open texture of the body, and should crack or craze when exposed to changes of temperature. Secondly, that for coating the ware with the glaze, it is necessary to dip the article in the vitreous mixture finely ground, and kept in suspension in water; consequently, if it were in the raw state when this was done, the adhesion of the particles would be so small, that they would readily dissolve in the liquid. It is customary, therefore, to expose the goods first to a hard fire, which, according to the size of the ovens and the quality of the ware, may last from forty to fifty hours.

From the biscuit oven, the goods, if they are to be left white, may be sent to be glazed; but if they are to be decorated with a printed pattern, they must be forwarded to the printing department. Printing on pottery is comparatively a modern invention, its chief advantage being the cheap rate of production. Up to the last century, the goods were always painted by hand: a slow, but it must be confessed, a more artistic process, as the work executed in this way, even of an inferior kind, will exhibit a freedom of touch and facility of execution, which will make it attractive and preferable to the formality of a printed pattern, however rich or complicated it may be. This superiority is sufficiently illustrated by comparing monochrome patterns of Italian majolica, Delft, and Chinese, with the modern printed ware of the same colour.

Public taste has so wonderfully improved lately, that, for my part, I have no doubt that we shall soon have a special class of artists trained to execute, by hand, cheap and simple decorations for those purchasers who are not satisfied with printed decoration.

To what extent the introduction of printing on pottery has hindered the progress of art education in Staffordshire, is a question on which people may entertain different opinions; but we might ask, what amount of artistic work we might not do, if at the present time we had some hundreds of artisans trained from their early years to that style of painting? However that may be, the process of transferring printed patterns to biscuit ware was considered a great step, and one which contributed largely to the extension of the earthenware trade.

Liverpool and Worcester claim the priority for this invention, towards the year 1752. It is a fact that shortly after that date, Staffordshire potters used to send their wares to Messrs. Sadler and Guy-Green, of Liverpool, to be printed; and there is also every reason to believe that about the same time it was introduced at the Worcester works, then under the management of Dr. Wall, by an engraver named Hancock.

The process of printing on pottery does not differ very materially from that used for transferring to paper a design from an ordinary copper-plate. There are, however, these differences, that a metallic colour is used instead of lampblack, and that a fine tissue paper is specially made for that purpose. When that paper, with the pattern printed upon it, is laid on the ware, face downwards, the colours adhere strongly to the biscuit, which, being porous and aluminous, has a great affinity for the oil with which they have been mixed. After rubbing the back of the print with a roll of flannel, to secure the adhesion of every portion of the pattern, the biscuit piece is plunged in water, and the paper comes off quite freely, the whole of the colour sticking fast to the ware.

Previous to glazing, the printed ware must be brought to a red heat, for the sole object of burning the oil mixed with the colour. This is done in kilns, called hardening-on kilns.

The colours in use for printing under the glaze are not many; as few only of the preparations made with metallic oxides can, when brought to a red heat, stand the action of the glazes under which they are laid. Most of them in this case will be dissolved and considerably weakened, if they do not even completely disappear. Cobalt, and the preparations made from chromates, are the most resisting, and, when well prepared, the glaze in melting over them will bring out the colour with increased beauty.

The necessity for covering the biscuit with glaze to stop the absorption of liquids or greasy substances, which would find their way into its interior and would stain it, is so obvious, that I do not think it necessary to dwell on the importance of this operation. I have stated already that it was used by the Egyptians and Assyrians, who knew most of the saline mixtures by which white and coloured glazes could be obtained; but these, which for the greatest part were alkaline silicates, could not have resisted the action of time as they have done, if a certain amount of silicate of lead had not made them permanent. They found this material in the sulphide of lead, which by the silica it contains, or that which it meets on the body of the ware, gives a glaze, which stands exposure to damp better than any other. That this mineral was used in remote antiquity, proofs are numerous. I recollect, amongst others, some small shalti, or sepulchral figures, made in Egypt more than two thousand years ago, of which the red parts, such as the faces and hands, have been glazed in this way. My opinion is, that it was used by the Greeks, in connection with the black oxide of iron, to produce the black colour used in the decoration of their vases, and it might some day prove that it was an indispensable material in the preparation of the red smear, which is the characteristic feature of the Samian ware. At all events it is with this single material, stained with metallic oxides, that the Arabs glazed their rich-looking pottery, and the same was used afterwards for our encaustic tiles and our common pottery, from the time of Elizabeth down to the middle of the last century. Lately, however, the science of making glazes has considerably improved, and a variety of new substances have been introduced. To prepare a glaze is one of the most delicate operations possible, and failures are attended with most serious consequences. The conditions to be fulfilled are many. It must not be too fusible nor too hard, either of which conditions would make it dull or apt to craze; and it must be transparent, otherwise the colours underneath would not be clear. It may happen that a glaze which apparently seems good when it comes out from the oven, will craze when a few months, or perhaps years, have elapsed. Generally, the less alumina that there is in the biscuit, the easier is the adaptation of the glaze, and this accounts for the soft porcelains being easier to manage in this respect than ordinary earthenwares.

The materials used for the foundation of glazes are in principle the same as those for the body, viz. silica, in the form of flint, or sand and felspar, pure or mixed with other components in the granitic rocks, called Cornish stone. These are the hard materials to be vitrified by the fluxes, which are carbonate or oxide of lead, boracic acid or borax, potash or soda, carbonate of lime or barytes. There is no definite receipt for mixing, and they may be combined in a variety of ways. Every manufacturer has receipts of his own, and I must say that some make their glazes a great deal better than others. They are rather expensive, chiefly owing to the increased price of borax, a material of comparatively modern use, which, being apt to promote the brilliancy of the wares and the beauty of the various colours, is now extensively used. When the components of the glazes are not soluble in water, it may be sufficient to have them finely ground in water. But if any soluble salt, such as borax, nitre, or soda, is employed, it is necessary to render them insoluble, by vitrifying them together with other substances. This may be effected in crucibles, or, still better, in reverberatory furnaces, where a large quantity may be melted more conveniently. In this case, when the mass is well liquefied by the intensity of the heat, it is run into cold water, which, cooling it suddenly, causes it to break into small fragments. This is called a fritt; and when it is sent to the mill, any other insoluble material may be added to it if necessary. To lay a thin coat of glaze on the surface of earthenware, is a most expeditious process. Advantage is taken of the porous nature of the biscuit, which, being dipped in the liquid slip, rapidly absorbs the water, while the solid particles of the glaze, which, however fine, could not follow the water to its interior, are found coating the surface. As the pieces are removed from this bath before the pores of the clay are saturated with water, they are seen to dry almost directly.

After this, the last operation consists in firing the pieces a second time, to give them that neat and finished look which belongs to glazed substances. The saggers, ovens, and the mode of conducting the fire do not differ in this case from those used for making biscuit. The ovens are, however, smaller, and the saggers cannot be packed so closely with the different articles, as every piece has to be isolated, otherwise the glaze in melting would cause them to stick together. To provide against this, small implements made of clay cut in different forms are used, and, not to disfigure the ware, are contrived in such a way that the points of contact between them and the pieces should be as small as possible. This second firing does not take more than fifteen or eighteen hours, and this completes the series of operations, by which ordinary earthenware sold in the white or printed state may be produced. The reader must understand that the majority of these processes are also applicable to the manufacture of china, or any other glazed pottery, with some modifications which I shall take the opportunity of noticing, when speaking of these varieties.

Pottery may be decorated in a great number of ways, and the operations are so varied that I cannot describe them all intelligibly, should I attempt to do so in my limited space. I shall consequently speak only of the paintings executed on the surface. This necessitates the use of colours specially prepared and made from two distinct materials; the bases and the fluxes. The bases are generally metallic oxides or highly oxidized compounds; the fluxes are vitreous substances, similar to the glazes, but softer, whose function is, to fix the colours permanently on the ware. When both, after being intimately ground together, are fired at a moderate heat on the article, the fluxes will cause the colour of the bases to look more vigorous and brighter, the effect being rather similar to that of an oil or transparent varnish on ordinary body colour. For this object, they must have very little chemical action, and be sufficiently soft to act in a moderate quantity. If, by carelessness or accident, the temperature is raised to a degree higher than the one exactly required, new compounds are formed, and the alteration of the colour is the consequence. There are some instances in which no fluxes are required; this is the case, when the ware has been coated with a glaze sufficiently fusible to allow the bases to sink in it, as soon as it begins to soften under the influence of heat. By this process more force and effect are obtained. It is, however, seldom used, for this reason, that from the care and attention which it requires in the superintendence of the firing, the manufacturer would run greater risks, and, being unable to use large ovens, would not turn out the same quantity of ware. Altogether it is a very expensive process.

Modern chemistry has placed at the disposal of colour makers new compounds which have made the preparation of fluxes comparatively easy. At the present time two classes are required: those in which the oxides of lead predominate, and those chiefly made with borax, which on account of its great purity is used in almost every flux, and is of great service for those colours which, like the pinks and purples, would suffer from the presence of lead.

The preparation of painting colours is a little more complicated, and each requires a different treatment. The number of those found in the trade is rather large, and each artist has his favourite maker. In this, as in any other kind of painting, beginners are apt to think that they will be assisted by the use of a great variety of tints, when they will learn by more experience, that a very limited number is sufficient. I cannot undertake to give any receipts for those who might wish to prepare these themselves; I only mention the name of the substances necessary to secure each of the essential colours.

White is not a colour, but when wanted on a coloured body, it is procured by an enamel prepared with the oxide of tin. Light yellow requires the oxides of lead and antimony. Orange will require the same, with an addition of deutoxide of iron. The hydrate of peroxide of the same metal will give a golden buff. The subchromate of lead gives a very bright red, but it is very unsafe and mixes badly; the reds made by calcining the common sulphate of iron are preferred. From this, according to the degree of fire, all shades of red may be got, from an orange red to a deep purple brown. The pinks, purples, and crimsons are made from the precipitate of cassius; this is obtained by pouring a weak solution of tin in the chloride of gold. The dark blue is a triple silicate of cobalt, which, by the admixture of the white oxide of zinc, may be converted into a brighter blue. The green oxide of chrome is the base of all greens, the tint of which is modified by cobalt for the blue greens, and antimony for the yellow greens. The chromate of iron, a mineral coming in large quantities from South America, is the base of all browns. The black may be got from the mixture of various oxides, but the best is that made from the oxide of iridium. Besides the above, there is another class of colours in which the oxides are thoroughly combined with the fluxes, such as the greens made from copper and the transparent blues, which are ground colours, and must be classified with the glazes. When painting colours are fired with their respective fluxes, they are very permanent, and will not only resist ordinary atmospheric influences, but also the action of every gas or mineral acid (the fluoric excepted). This seems an advantage in favour of painting on pottery, and one which ought to give them an additional value; in reality, however, artistic merit ranks above all other considerations, and unless the work is original, connoisseurs in pottery will hardly take this into account.

Several oils possessing drying properties, such as those of lavender, aniseed, or turpentine, are mixed with the colours, which, from the fact of containing vitreous substances, would work badly; even with their assistance, it requires a certain amount of skill to master the process. We must not make too much, however, of this difficulty, generally exaggerated by the ignorance of apprentices in what constitutes the very principles of their profession. When parents, in perfect ignorance of the abilities of their son, have decided, after putting their heads together, that he shall be a painter, sometimes for no other consideration than that they can get him admission into a porcelain manufactory, or that this is the nearest to their home, the boy has not the least notion of what is before him, and hardly knows that he will have to learn that very difficult thing, drawing. No wonder then, if his deficiency in this will not allow him to produce, we will not say good, but saleable paintings, unless he has spent a dozen years on his trial. On the contrary, to one well prepared by the study of art – one who, before he sets to his work, has a clear conception of the effect which he wishes to produce – the process will not stand in the way, and he will master it in the course of a few weeks.

To induce talented men to devote their time to the decoration of pottery, is perhaps the greatest difficulty met with by our leading manufacturers. As long as the making of the ware only was concerned, they had to call for the assistance of practical men, such as potters, chemists, or engineers, the number of whom is fortunately great in England, and whose services can be secured by money. The same thing is not so easy in the matter of art. Up to a recent date, painting on pottery was not considered as the high road to fortune, and artists preferred to try their chance in oil or water-colour painting, fully aware that they would have to fight against an army of competitors, and to be satisfied with very small incomes, unless, by their, then problematic, genius, they could cut their way to the front. Since, however, the rage (there is no other word for it) for well decorated pottery has spread in almost every class of society, the prices paid for good work are more remunerative, and artists like Solon, Mussill, and Coleman, can make artistic pottery their special business.

Royal Academicians like Poynter and Marks have thought it not beneath them to prepare cartoons for Minton, and it is probable that others would follow in the same path if, with the assistance of our chief potters, they could be initiated into some of the mysteries of the craft. No doubt they would find the study attractive, and there is no fear that, having once begun, they would not keep faithfully to it. For myself, I know of no such example.