Chambers's Edinburgh Journal, No. 455

Ozone, in scientific language, is described as 'a compound of oxygen analogous to the peroxide of hydrogen, or, that it is oxygen in an allotropic state—that is, with the capability of immediate and ready action impressed upon it.' Besides being produced by electrical discharges in the atmosphere, it can be obtained artificially by the passing of what is called the electrical brush into the air from a moist wooden point, or by electrolyzed water or phosphorus. The process, when the latter substance is employed, is to put a small piece, clean scraped, about half an inch long, into a large bottle which contains just so much of water as to half cover the phosphorus, and then closing the mouth slightly, to guard against combustion, to leave it standing for a time in a temperature of about 60 degrees. Ozone soon begins to be formed, as shewn by the rising of a light column of smoke from the phosphorus, which, at the same time, becomes luminous. In five or six hours, the quantity will be abundant, when the bottle is to be emptied of its contents, washed out, and closed for use and experiment.

Whichever way the ozone be produced, it is always identical in its properties; and these are described as numerous and remarkable. Its odour is peculiar, resembling that of chlorine, and, when diluted, cannot be distinguished from what is called the electric smell. When largely diffused in atmospheric air, it causes unpleasant sensations, makes respiration difficult, and, by acting powerfully on the mucous membranes, produces catarrhal effects; and as such air will kill small animals, it shews that pure ozone must be highly injurious to the animal economy. It is insoluble in water, is powerfully electromotive, and is most strikingly energetic in numerous chemical agencies, its action on nearly all metallic bodies being to carry them at once to the state of peroxide, or to their highest point of oxidation; it changes sulphurets into sulphates, instantaneously destroys several gaseous compounds, and bleaches indigo, thus shewing its analogy with chlorine.

In proceeding to the account of his experiments, M. Schoenbein shews, that gases can be produced by chemical means, which exercise an oxidizing influence of a powerful nature, especially in their physiological effects, even when diffused through the atmosphere in very minute quantities: also, that owing to the immense number of organic beings on the earth, their daily death and decomposition, an enormous amount of gases is produced similar to those which can be obtained by artificial means; and besides these, a quantity of gaseous or volatile products, 'whose chemical nature,' as the author observes, 'is as yet unknown, but of which we can easily admit that some, at least, diffused through the air, even in very small quantities, and breathed with it, exert a most deplorable action on the animal organism. Hence it follows, that the decomposition of organic matters ought to be considered as one of the principal causes of the corruption of the air by miasmatic substances. Now, a continuous cause, and acting on so vast a scale, would necessarily diffuse through the atmosphere a considerable mass of miasmatic gases, and accumulate them till at length it would be completely poisoned, and rendered incapable of supporting animal life, if nature had not found the means of destroying these noxious matters in proportion as they are produced.'

The question then arises: What are the means employed for this object? M. Schoenbein believes that he has found it in the action of ozone, which is continually formed by the electricity of the atmosphere, and is known to be a most powerful agent of oxidation, causing serious modifications of organic bodies, and, consequently, of their physiological action. 'To assure myself,' he pursues, 'that ozone destroys the miasma arising from the decomposition of animal matters, I introduced into a balloon containing about 130 pints of air, a piece of flesh weighing four ounces, taken from a human corpse, and in a very advanced state of putrefaction. I withdrew it after a minute; the air in the balloon had acquired a strong and very repulsive odour, shewing that it was charged with an appreciable quantity—at least for the smell—of miasm caused by the putrefaction.

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